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{"sheet":"Intro","index":0,"n_rows":89,"n_cols":14,"rows_kept":89,"cut":false,"hidden":false,"merged":[[87,3,87,6],[88,3,88,6]]}
[null,"FERTILIZER ENVIRONMENTAL EXPOSURE (FEE) TOOL"]
[null,"INTRODUCTION"]
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[null,null,"SPERC","Code","Description","Air (%)","Soil (%)","Surface water (%)"]
[null,null,1,"8e.1.v2","Outdoor use - direct application of solid fertilizers to soil; surface spreading",0,100,0]
[null,null,2,"8e.2.v2","Outdoor use - direct application of solid or liquid fertilizers to soil; incorporation, placement, mixing, seed treatment, drip irrigation",0,100,0]
[null,null,3,"8e.3.v2","Outdoor use - application of fertilizers by helicopter",0,100,3.32]
[null,null,4,"8e.4.v3","Outdoor use - spray application of liquid fertilizers; soil surface spreading, sprinkler, pivot, foliar spray, slurry",0,100,{"$f":"15.7/10","v":1.5699999999999998}]
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[null,null,null,null,null,null,null,null,null,null,"Name","Formula","CAS nr","EC nr"]
[null,null,null,null,null,null,null,null,null,null,"Copper"]
[null,null,null,null,null,null,null,null,null,null,"Copper chloride","CuCl","7758-89-6","231-842-9"]
[null,null,null,null,null,null,null,null,null,null,"Copper di(acetate)","Cu(CH3COO)2","142-71-2, \n6046-93-1","205-553-3"]
[null,null,null,null,null,null,null,null,null,null,"Copper dichloride","CuCl2","7447-39-4, \n10125-13-0","231-210-2"]
[null,null,null,null,null,null,null,null,null,null,"Copper dihydroxide","Cu(OH)2","20427-59-2","243-815-9"]
[null,null,null,null,null,null,null,null,null,null,"Copper dinitrate","Cu(NO3)2","3251-23-8, \n10031-43-3","221-838-5"]
[null,null,null,null,null,null,null,null,null,null,"Copper oxide","CuO","1317-38-0","215-269-1"]
[null,null,null,null,null,null,null,null,null,null,"Copper sulphate","CuSO4","7758-98-7, \n7758-99-8","231-847-6"]
[null,null,null,null,null,null,null,null,null,null,"Copper(2+) ion hydroxide nitrate","Cu(OH)(NO3)","12158-75-7","439-590-3"]
[null,null,null,null,null,null,null,null,null,null,"Copper(II) carbonate--copper(II) hydroxide (1:1)","CuCO3-Cu(OH)2","12069-69-1","235-113-6"]
[null,null,null,null,null,null,null,null,null,null,"Dicopper oxide","Cu2O","1317-39-1","215-270-7"]
[null,null,null,null,null,null,null,null,null,null,"Dicopper chloride trihydroxide","Cu2Cl(OH)3","1332-40-7, \n1332-65-6","215-572-9"]
[null,null,null,null,null,null,null,null,null,null,"Dicopper hydroxide phosphate","Cu2(OH)(PO4)","12158-74-6","235-285-2"]
[null,null,null,null,null,null,null,null,null,null,"Zinc"]
[null,null,null,null,null,null,null,null,null,null,"Zinc bis(dihydrogen phosphate)","Zn(H2PO4)2","13598-37-3","237-067-2"]
[null,null,null,null,null,null,null,null,null,null,"Trizinc bis(orthophosphate)","Zn3(PO4)2","7779-90-0","231-944-3"]
[null,null,null,null,null,null,null,null,null,null,"Zinc borate","ZnHBO3","1332-07-6","215-566-6"]
[null,null,null,null,null,null,null,null,null,null,"Zinc chloride","ZnCl2","7646-85-7","231-592-0"]
[null,null,null,null,null,null,null,null,null,null,"Zinc hydroxide","Zn(OH)2","20427-58-1","243-814-3"]
[null,null,null,null,null,null,null,null,null,null,"Zinc nitrate","Zn(NO3)2","7779-88-6, \n10196-18-6","231-943-8"]
[null,null,null,null,null,null,null,null,null,null,"Zinc oxide","ZnO","1314-13-2, \n7440-66-6","215-222-5"]
[null,null,null,null,null,null,null,null,null,null,"Zinc sulphate","ZnSO4","7446-19-7, \n7446-20-0, \n7733-02-0","231-793-3"]
[null,null,null,null,null,null,null,null,null,null,"Ammonium zinc chloride","Zn(NH4)2Cl4","52628-25-8","258-054-8"]
[null,null,null,null,null,null,null,null,null,null,"Carbonic acid, zinc salt, basic","Zn(x/2+y).(OH)x.(CO3)y","51839-25-9","257-467-0"]
[null,null,null,null,null,null,null,null,null,null,"Zinc carbonate","ZnCO3","3486-35-9","222-477-6"]
[null,null,null,null,null,null,null,null,null,null,"Manganese"]
[null,null,null,null,null,null,null,null,null,null,"Manganese sulphate","MnSO4","7785-87-7, \n10034-96-5","232-089-9"]
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[null,"Tool developed by ARCHE Consulting"]
[]
[null,null,null,null,"Contact details:"]
[null,null,null,null,"ARCHE Consulting - Koen Oorts"]
[null,null,null,null,"koen.oorts@arche-consulting.be"]
[]
[null,"Version log"]
[null,"Version","Date","Implemented changes",null,null,null,"Authors"]
[null,"1.1","2017-09-25","V1 final first version FEE-tool",null,null,null,"Koen Oorts, Sabine Navis"]
[null,"1.2","2019-10-24","Modifications and bug fixes:\n\nIntro\n- A list of substances for the micronutrients Cu, Zn and Mn covered by the FEE tool has been added\n\nInput\n- The word \"Substance\" in Step 1 and 3 has been replaced by \"Nutrient (element) / co-formulant\"\n- The option for soil incorporation has been added to Step 5 (i.e. ploughing of soil up to 20 cm, within 3 days after application)\n- The option for runoff reduction (vegetative filter strips) has been included to Step 5 (fixed values of 60% and 80% reduction, based on FOCUS calc)\n- The macro behind the reset button in the Input sheet is adapted to the changes\n\nOutput\n- For calculations of the PEC surface water, the water solubility has been included in the Clocal and PEC local calculations (instead of in the Csurface water conc)\n- PEC sediment is calculated directly from PEC local surface water, using equilibrium partitioning (concentration averaged over 30 days instead of 365 days)\n- Max safe application rate for soil is now irrespective of the application rate entered in 'Input' sheet\n\nCalculations\n- Adjustment to calculation of runoff (first order equation, max set to 5%; FOCUS default)\n- The calculations have been extended to include the option for soil incorporation and runoff RMMs, if selected at Step 5 of Input sheet\n",null,null,null,"Koen Oorts, Sabine Navis"]
[null,null,null,"\nConc_sw\n- The calculation period for concentrations in surface water has been extended from 100 to 365 days, to allow for larger time between applications\n\nMicro-nutrient endpoints\n- The PNEC soil and PNEC sediment for manganese have been updated, in line with the REACH registration dossier\n- A list of substances for the micronutrients Cu, Zn and Mn covered by the FEE tool has been added"]

{"sheet":"Input","index":1,"n_rows":57,"n_cols":6,"rows_kept":57,"cut":false,"hidden":false,"merged":[[43,1,44,1],[2,2,2,3],[10,2,10,3],[12,2,12,3],[11,2,11,3],[17,4,17,7],[7,4,7,5],[6,4,6,5],[3,2,3,3],[43,2,43,3]]}
[null,"FERTILIZER ENVIRONMENTAL EXPOSURE (FEE) TOOL"]
[null,"INPUT"]
[null,"1.  Nutrient (element) / co-formulant","Copper"]
[null,"2.  Specific Environmental Release Category (SpERC)","SPERC 1: Outdoor use - direct application of solid fertilizers to soil; surface spreading"]
[null,"3.  Single or multiple applications per growing season?","Single"]
[null,"     Total annual use rate of nutrient (element) / co-formulant",null,"[kg/ha/year]",{"$f":"IF(AND(C5=\"Single\",Number_of_applications>1),\"ERROR: in case of more than 1 application per growing season select 'Multiple' at Step 3\",\" \")","v":" "}]
[null,{"$f":"IF(C5=\"Multiple\",\"     Number of applications\",\"\")","v":""},null,{"$f":"IF(C5=\"Multiple\",\"-\",\"\")","v":""},{"$f":"IF(AND(C5=\"Single\",Number_of_applications>1),\"ERROR: in case of single application, leave field empty or enter 1\",IF(AND(C5=\"Multiple\",Number_of_applications<2),\"ERROR: in case of multiple applications per growing season, value should be >1\",\" \"))","v":" "}]
[null,{"$f":"IF(C5=\"Multiple\",\"     Time between applications\",\"\")","v":""},null,{"$f":"IF(C5=\"Multiple\",\"[days]\",\"\")","v":""}]
[null,{"$f":"IF(C5=\"Multiple\",\"     Fertilizer use rate per application\",\"\")","v":""},{"$f":"IF(Single_Multi=\"Multiple\",APPL_rate_year/Number_of_applications,\"\")","v":""},{"$f":"IF(C5=\"Multiple\",\"[kg/ha]\",\"\")","v":""}]
[null,"4.  Refinement options",null,{"$f":"IF(Substance=\"-> Other\",\"Provide % available for runoff\",\"\")","v":""},"optional if at Step 1 \"Other\" is selected (if specific data are available)"]
[null,"    Crop type","Generic crop"]
[null,"    Crop growth stage (BBCH)","Bare soil, BBCH 00-09"]
[null,"    European crop yield scenario","Low"]
[null,"    Crop concentration",null,"[g/t]","only mandatory if at Step 1 \"Other\" is selected (enter 0 if unknown); optional if specific data are available"]
[null,"    Crop yield",null,"[t/ha]","only mandatory if at Step 1 \"Other\" is selected (enter 0 if unknown); optional if specific data are available"]
[null," 5.  Risk management measures (RMM) *",null,"[% drift reduction]"]
[null,null,null,"soil incorporation","ploughing up to 20 cm, only if within 3 days after application (and if bare soil is indicated at Crop growth stage)"]
[null,null,null,"[% runoff reduction]","corresponding to vegetative filter strips of 10-12m and 18-20m resp. (FOCUS, 2007)"]
[]
[null,"* To be justified, and translated into specific RMMs in correspondence with (national) requirements and product labelling"]
[]
[null,{"$f":"\"Nutrient (element) / co-formulant properties: \" & Substance & \" **\"","v":"Nutrient (element) / co-formulant properties: Copper **"},"Standard parameters","Refined parameters","Unit","Comments"]
[null,"Nutrient (element) / co-formulant",{"$f":"IF(Substance=\"-> Other\",\"Enter substance name\",Substance)","v":"Copper"},null,"-"]
[null,"Molecular weight ",{"$f":"IF(MOLW_M>0,\"\",VLOOKUP(Substance,'Micro-nutrient endpoints'!$B$4:$Q$9,3,FALSE))","v":63.55},null,"g/mol"]
[null,"Water solubility at 25°C",{"$f":"IF(SOL_M>0,\"\",VLOOKUP(Substance,'Micro-nutrient endpoints'!$B$4:$Q$9,4,FALSE))","v":100},null,"mg/L","Water solubility; value cannot be 0"]
[null,"Vapour pressure at 25°C",{"$f":"IF(VP_M>0,\"\",VLOOKUP(Substance,'Micro-nutrient endpoints'!$B$4:$Q$9,5,FALSE))","v":9.9999999999999995E-7},null,"Pa","Vapour pressure; value cannot be 0"]
[null,"Henry coefficient",{"$f":"IF(Henry_M>0,\"\",VLOOKUP(Substance,'Micro-nutrient endpoints'!$B$4:$Q$9,6,FALSE))","v":3.9999999999999998E-6},null,"Pa*m3/mol","Henry coefficient; value cannot be 0"]
[null,"Volatilization during application",{"$f":"IF(Substance=\"-> Other\",\"Select from dropdown menu\",0)","v":0},"Default (inorganics)","% dropdown menu","For organics: % volatilization depending on volatility class selected from dropdown menu"]
[null,"Log octanol-water partition coefficient",null,null,"-","Not relevant for inorganics"]
[null,"Partition coefficient organic carbon-water (Koc)",null,null,"L/kg dw","Not relevant for inorganics; if \"Other\" is selected at Step 1, provide Koc or Kpsoil (value cannot be 0)"]
[null,"Partition coefficient solid-water in soil (Kpsoil)",{"$f":"IF(Kpsoil_M=\"\",(VLOOKUP(Substance,'Micro-nutrient endpoints'!B4:Q9,7,FALSE)),\"\")","v":2120},null,"L/kg dw","Substance specific measured Kpsoil values are used as default input"]
[null,"Partition coefficient solid-water of susp. matter (Kpsusp)",{"$f":"IF(Kpsusp_M=\"\",(VLOOKUP(Substance,'Micro-nutrient endpoints'!B4:Q9,8,FALSE)),\"\")","v":30246},null,"L/kg dw","Substance specific measured Kpsusp values are used as default input"]
[null,"Biodegradability class",{"$f":"IF(Substance=\"-> Other\",\"Select from dropdown menu\",\"Not biodegradable\")","v":"Not biodegradable"},"Not biodegradable","dropdown menu","For organics: select from drop-down menu. For inorganics: default is set to 1000000 days"]
[null,"Half-life biodegradation in soil",{"$f":"IF(AND(Substance=\"-> Other\",Half_life_soil_M>0),\"\",DT50_soil)","v":1000000},null,"days"]
[null,"Half-life biodegradation in surface water ",{"$f":"IF(AND(Substance=\"-> Other\",DT50bio_water_sed_M>0),\"\",DT50_water)","v":1000000},null,"days"]
[null,"PEC regional soil",{"$f":"IF(Substance=\"-> Other\",\"Provide manual input\",(VLOOKUP(Substance,'Micro-nutrient endpoints'!$B$4:$Q$9,9,FALSE)))","v":14},null,"mg/kg dw","Provide manual input if \"Other\" is selected at Step 1"]
[null,"PEC regional freshwater",{"$f":"IF(Substance=\"-> Other\",\"Provide manual input\",(VLOOKUP(Substance,'Micro-nutrient endpoints'!$B$4:$Q$9,10,FALSE)))","v":2.9},null,"µg/L"]
[null,"PEC regional sediment",{"$f":"IF(Substance=\"-> Other\",\"Provide manual input\",(VLOOKUP(Substance,'Micro-nutrient endpoints'!$B$4:$Q$9,11,FALSE)))","v":67.5},null,"mg/kg"]
[null,"PNEC soil",{"$f":"IF(Substance=\"-> Other\",\"Provide manual input\",(VLOOKUP(Substance,'Micro-nutrient endpoints'!$B$4:$Q$8,13,FALSE)))","v":65},null,"mg/kg dw","Provide manual input if \"Other\" is selected at Step 1"]
[null,"PNEC freshwater",{"$f":"IF(Substance=\"-> Other\",\"Provide manual input\",(VLOOKUP(Substance,'Micro-nutrient endpoints'!$B$4:$Q$8,14,FALSE)))","v":7.8},null,"µg/L"]
[null,"PNEC sediment",{"$f":"IF(Substance=\"-> Other\",\"Provide manual input\",(VLOOKUP(Substance,'Micro-nutrient endpoints'!$B$4:$Q$8,15,FALSE)))","v":87},null,"mg/kg"]
[null,"** Standard parameters for micro-nutrients are based on information from the REACH dissemination website (unless otherwise stated); please check carefully for consistency with most recent dossier information"]
[]
[null,{"$f":"\"Scenario information: \" &SpERC","v":"Scenario information: SPERC 1: Outdoor use - direct application of solid fertilizers to soil; surface spreading"},"Input parameters e-fate model"]
[null,null,"Default assessment","Refined assessment","Unit","Comments"]
[null,"Fraction available for drift (during application)",{"$f":"VLOOKUP(SpERC,'Crop parameters'!B4:D38,3,FALSE)","v":0},{"$f":"IF(Crop_choice=\"Generic crop\",\"\",IF(SpERC=\"SPERC 4: Outdoor use - spray application of liquid fertilizers; soil surface spreading, sprinkler, pivot, foliar spray, slurry\",VLOOKUP(Crop_choice,'Crop parameters'!B4:D38,3,FALSE),\"\"))","v":""},"%","Default: based upon choice of SPERC; refined: based on crop type"]
[null,"Drift refinement, after reduction based on RMM","not considered",{"$f":"IF(AND(SpERC=\"SPERC 4: Outdoor use - spray application of liquid fertilizers; soil surface spreading, sprinkler, pivot, foliar spray, slurry\",Drift_refined<>\"\",Drift_M>0),Drift_refined*(1-Drift_M/100),IF(AND(SpERC=\"SPERC 4: Outdoor use - spray application of liquid fertilizers; soil surface spreading, sprinkler, pivot, foliar spray, slurry\",Crop_choice=\"Generic crop\",Drift_M>0),Drift_D*(1-Drift_M/100),IF(AND(SpERC=\"SPERC 3: Outdoor use - application of fertilizers by helicopter\",Drift_M>0),Drift_D*(1-Drift_M/100),\"\")))","v":""},"%","Refined assessment only: drift reduction based upon selection RMM"]
[null,"Fraction available for run-off (30 days after application)",{"$f":"IF(AND(Substance=\"-> Other\",Runoff_M>0),Runoff_M,VLOOKUP(SpERC,'SpERC details'!B5:C8,2,FALSE))","v":3.8542077816643427E-2},{"$f":"IF(AND(SpERC=\"SPERC 4: Outdoor use - spray application of liquid fertilizers; soil surface spreading, sprinkler, pivot, foliar spray, slurry\",Crop_interception_M<>\"\"),Runoff_D*(1-Crop_interception_M/100),IF(AND(SpERC=\"SPERC 1: Outdoor use - direct application of solid fertilizers to soil; surface spreading\",Crop_interception_M<>\"\"),Runoff_D*(1-Crop_interception_M/100),IF(AND(SpERC=\"SPERC 3: Outdoor use - application of fertilizers by helicopter\",Crop_interception_M<>\"\"),Runoff_D*(1-Crop_interception_M/100),\"\")))","v":""},"%","Depending on crop cover (SPERC 3 and 4) or developmental stage (SPERC 1)"]
[null,"Runoff reduction, based on crop type and growth stage","not considered",{"$f":"IF(Crop_cover=\"Bare soil, BBCH 00-09\",\"\",IF(Crop_choice=\"Generic crop\",VLOOKUP(SpERC,'Crop parameters'!B5:N38,MATCH(Crop_cover,'Crop parameters'!B5:N5,FALSE),FALSE),IF(SpERC=\"SPERC 4: Outdoor use - spray application of liquid fertilizers; soil surface spreading, sprinkler, pivot, foliar spray, slurry\",VLOOKUP(Crop_choice,'Crop parameters'!B5:N38,MATCH(Crop_cover,'Crop parameters'!B5:N5,FALSE),FALSE),VLOOKUP(SpERC,'Crop parameters'!B5:N38,MATCH(Crop_cover,'Crop parameters'!B5:N5,FALSE),FALSE))))","v":""},"%","Only for refined assessment: based on selected crop type and growth stage"]
[null,"Runoff reduction based on soil incorporation","not considered",{"$f":"IF(AND(Crop_cover=\"Bare soil, BBCH 00-09\",Soil_incorp=\"yes\"),VLOOKUP(SpERC,'SpERC details'!B5:D8,3,FALSE),\"\")","v":""},"%","Only for refined assessment, if soil incorporation directly after application"]
[null,"Runoff refinement, based on RMM","not considered",{"$f":"IF(Runoff_RMM=\"\",\"\",IF(AND(Runoff_refined=\"\",Runoff_refined_soil_incorp=\"\"),Runoff_D*(1-Runoff_RMM/100),IF(Runoff_refined=\"\",Runoff_refined_soil_incorp*(1-Runoff_RMM/100),Runoff_refined*(1-Runoff_RMM/100))))","v":""},"%","Only for refined assessment: based on selection RMM"]
[null,"Crop elemental concentration","not considered",{"$f":"IF(Crop_conc_M<>\"\",Crop_conc_M,IF(Substance=\"-> Other\",\"Provide manual input in cell C14\",IF(Crop_conc_M=\"\",(VLOOKUP(Crop_choice,'Crop parameters'!B5:G38,MATCH(Substance,'Crop parameters'!B5:G5,FALSE),FALSE)))))","v":0},"g substance/t","Based upon literature search for micronutrients, or manual input"]
[null,"Crop yield","not considered",{"$f":"IF(Crop_yield_M<>\"\",Crop_yield_M,IF(Substance=\"-> Other\",\"Provide manual input in cell C15\",IF(Crop_yield_M=\"\",VLOOKUP(Crop_choice,'Crop parameters'!B5:J38,MATCH(Crop_quality,'Crop parameters'!B5:J5,FALSE),FALSE))))","v":0},"t yield/ha","Based on crop specific Eurostat data (European crop yield scenarios) or manual input"]
[null,"Crop offtake","not considered",{"$f":"IF(OR(Crop_conc_D=0,Crop_yield_D=0), 0,Crop_conc_D/1000*Crop_yield_D)","v":0},"kg substance/ha/y","Calculated from crop element concentration and crop yield scenario"]
[]
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[null,null,null,null,null,"Tool developed by ARCHE Consulting\n© 2017"]

{"sheet":"Output","index":2,"n_rows":35,"n_cols":13,"rows_kept":35,"cut":false,"hidden":false,"merged":[[20,2,20,7],[20,8,20,9],[20,10,20,11]]}
[null,"FERTILIZER ENVIRONMENTAL EXPOSURE (FEE) TOOL"]
[null,"OUTPUT"]
[]
[null,"Exposure scenario"]
[null,"Substance",{"$f":"Substance","v":"Copper"}]
[null,"SpERC",{"$f":"SpERC","v":"SPERC 1: Outdoor use - direct application of solid fertilizers to soil; surface spreading"}]
[null,"Application rate (total)",{"$f":"APPL_rate_year & \" \" & \"kg/ha/year\"","v":" kg/ha/year"}]
[null,"Number, timing applications",{"$f":"IF(Single_Multi=\"Single\",\"1 application\",Number_of_applications & \" applications, \" & Time_between_applications & \" days between applications\")","v":"1 application"}]
[null,"Crop type",{"$f":"Crop_choice","v":"Generic crop"}]
[null,"Crop growth stage",{"$f":"Crop_cover","v":"Bare soil, BBCH 00-09"}]
[null,"European crop yield scenario",{"$f":"Crop_quality","v":"Low"}]
[null,"Risk management measures",{"$f":"IF(Drift_M<>\"\",Drift_M&\"% drift reduction\",\"None\")","v":"None"}]
[]
[null,"Emission estimate"," [kg/ha]"," [%]"]
[null,"Volatilization",{"$f":"App_eq*Vol_perc/100","v":0},{"$f":"C15/$C$20*100","v":{"$error":"#DIV/0!"}}]
[null,"Drift",{"$f":"App_eq*Drift_perc*0.1/100","v":0},{"$f":"C16/$C$20*100","v":{"$error":"#DIV/0!"}}]
[null,"Runoff",{"$f":"App_eq*Runoff_perc/100","v":0},{"$f":"C17/$C$20*100","v":{"$error":"#DIV/0!"}}]
[null,"Crop offtake",{"$f":"Crop_offtake","v":0},{"$f":"C18/$C$20*100","v":{"$error":"#DIV/0!"}}]
[null,"Soil accumulation",{"$f":"Input_soil","v":0},{"$f":"C19/$C$20*100","v":{"$error":"#DIV/0!"}}]
[null,null,{"$f":"SUM(C15:C19)","v":0},{"$f":"SUM(D15:D19)","v":{"$error":"#DIV/0!"}}]
[null,null,"Exposure assessment",null,null,null,null,null,"Effect assessment",null,"Risk characterisation"]
[null,"Environmental compartment","C local \nyear 1","C local \nyear 10","PEC regional","PEC total\nyear 1","PEC total\nyear 10","Unit","PNEC","Unit","RCR year 1","RCR year 10"]
[null,"Soil (agricultural)",{"$f":"(1/(ktotal*time)*Csoil1*(1-EXP(-ktotal*time)))","v":0},{"$f":"(1/(ktotal*time)*Csoil10*(1-EXP(-ktotal*time)))","v":0},{"$f":"IF(PECreg_soil_M>0,PECreg_soil_M,(VLOOKUP(Substance,'Micro-nutrient endpoints'!$B$4:$Q$9,9,FALSE)))","v":14},{"$f":"Csoil_1_30+PEC_regional_soil","v":14},{"$f":"Csoil_10_30+PEC_regional_soil","v":14},"mg/kg dw",{"$f":"IF(Substance=\"-> Other\",PNEC_soil_M,PNEC_soil_D)","v":65},"mg/kg dw",{"$f":"PECsoil_total_1/PNEC_soil","v":0.2153846153846154},{"$f":"PECsoil_total_10/PNEC_soil","v":0.2153846153846154},"PEC local calculated as TWA conc in soil for 30 days after application; Eqn R.16-43"]
[null,"Freshwater (dissolved)",{"$f":"IF((1/(ktotal_water*time)*Csurfacewater1*(1-EXP(-ktotal_water*time)))<(SOL*1000),(1/(ktotal_water*time)*Csurfacewater1*(1-EXP(-ktotal_water*time))),(SOL*1000))","v":0},{"$f":"IF((1/(ktotal_water*time)*Csurfacewater10*(1-EXP(-ktotal_water*time)))<(SOL*1000),(1/(ktotal_water*time)*Csurfacewater10*(1-EXP(-ktotal_water*time))),(SOL*1000))","v":0},{"$f":"IF(PECreg_water_M>0,PECreg_water_M,(VLOOKUP(Substance,'Micro-nutrient endpoints'!$B$4:$Q$9,10,FALSE)))","v":2.9},{"$f":"IF(Cwater_1_30+PECregional_water<(SOL*1000),Cwater_1_30+PECregional_water,(SOL*1000))","v":2.9},{"$f":"IF(Cwater_10_30+PECregional_water<(SOL*1000),Cwater_10_30+PECregional_water,(SOL*1000))","v":2.9},"µg/L",{"$f":"IF(Substance=\"-> Other\",PNEC_water_M,PNEC_water_D)","v":7.8},"µg/L",{"$f":"PECwater_total_1/PNEC_water","v":0.37179487179487181},{"$f":"PECwater_total_10/PNEC_water","v":0.37179487179487181},"PEC local calculated as TWA conc in freshwater for 30 days after application; Eqn R.16-43"]
[null,"Sediment",{"$f":"((Ksusp_water/RHOsusp)*Cwater_1_30/1000*1000)","v":0},{"$f":"((Ksusp_water/RHOsusp)*Cwater_10_30/1000*1000)","v":0},{"$f":"IF(PECreg_sed_M>0,PECreg_sed_M,(VLOOKUP(Substance,'Micro-nutrient endpoints'!$B$4:$Q$9,11,FALSE)))","v":67.5},{"$f":"Csediment_1_30+PEC_regional_sediment","v":67.5},{"$f":"Csediment_10_30+PEC_regional_sediment","v":67.5},"mg/kg",{"$f":"IF(Substance=\"-> Other\",PNEC_sed_M,PNEC_sed_D)","v":87},"mg/kg",{"$f":"PECsediment_total_1/PNEC_sediment","v":0.77586206896551724},{"$f":"PECsediment_total_10/PNEC_sediment","v":0.77586206896551724},"PEC local based upon conc in surface water, calculated as 30-d TWA; Eqn. R.16-34"]
[null,"Groundwater",null,null,null,{"$f":"IF((PECsoil_total_1*RHOsoil_wet)/(Ksoil_water*1000)<SOL, (PECsoil_total_1*RHOsoil_wet)/(Ksoil_water*1000),SOL)","v":7.4849506320349259E-3},{"$f":"IF((PECsoil_total_10*RHOsoil_wet)/(Ksoil_water*1000)<SOL, (PECsoil_total_10*RHOsoil_wet)/(Ksoil_water*1000),SOL)","v":7.4849506320349259E-3},"mg/L",null,null,null,null,"Groundwater conc based upon conc in porewater agricultural soil, max is water solubility; Eqn. R.16-55"]
[]
[null,"Maximum safe application rate calculation"]
[null,"Most sensitive environmental compartment year 1",{"$f":"IF(MIN(Calculations!C74:C76)=Max_application_rate_soil_1,\"soil\",IF(MIN(Calculations!C74:C76)=Max_application_rate_freshwater_1,\"freshwater\",IF(MIN(Calculations!C74:C76)=Max_application_rate_sediment_1,\"sediment\")))","v":"soil"}]
[null,"Most sensitive environmental compartment year 10",{"$f":"IF(MIN(Calculations!C77:C79)=Max_application_rate_soil_10,\"soil\",IF(MIN(Calculations!C77:C79)=Max_application_rate_freshwater_10,\"freshwater\",IF(MIN(Calculations!C77:C79)=Max_application_rate_sediment_10,\"sediment\")))","v":"soil"}]
[null,"Target RCR",0.9]
[null,"Estimated max application rate year 1",{"$f":"MIN(Calculations!C74:C76)","v":1000},"kg/ha/year"]
[null,"Estimated max application rate year 10",{"$f":"MIN(Calculations!C77:C79)","v":1000},"kg/ha/year"]
[]
[null,null,null,null,null,null,null,null,null,"Tool developed by ARCHE Consulting © 2017"]

{"sheet":"Defaults","index":3,"n_rows":42,"n_cols":6,"rows_kept":42,"cut":false,"hidden":false,"merged":[[7,5,10,5]]}
[null,"FERTILIZER ENVIRONMENTAL EXPOSURE (FEE) TOOL"]
[null,"DEFAULTS"]
[]
[null,"Parameters","Value","Unit","Comments"]
[null,"Temperature (TEMP)",285,"°K","Table R.16-8 (12°C)"]
[null,"Depth (DEPTHsoil)",0.2,"m","Table R.16-15, agricultural soil"]
[null,"Depth soil runoff (DEPTHsoil_runoff)",0.02,"m","Worst-case assumption"]
[null,"Depth of the surface water (DEPTHwater)",0.3,"m","FOCUS Steps 1-2","Default scenario used:\n1 ha field, with surrounding shallow water body 1/10th of field size"]
[null,"Ratio field to water body (RATIO)",10,"-","FOCUS Steps 1-2"]
[null,"Density solid phase (RHOsolid)",2500,"kg/m3","Table R.16-8, general"]
[null,"Density water phase (RHOwater)",1000,"kg/m3","Table R.16-8, general"]
[null,"Density air (RHOair)",1.3,"kg/m3","Table R.16-8, general"]
[null,"Volume fraction water in soil (Fwater_soil)",0.2,"-","Table R.16-8, soil"]
[null,"Volume fraction air in soil (Fair_soil)",0.2,"-","Table R.16-8, soil"]
[null,"Volume fraction solids in soil (Fsolid_soil)",0.6,"-","Table R.16-8, soil"]
[null,"Weight fraction organic carbon in soil solids (Foc_soil)",0.02,"-","Table R.16-8, soil"]
[null,"Concentration of suspended matter in water, dry weight (SUSPwater)",15,"mg/L","Table R.16-8, surface water"]
[null,"Volume fraction solids in suspended matter (Fsolid_susp)",0.1,"-","Table R.16-8, susp.matter"]
[null,"Volume fraction water in suspended matter (Fwater_susp)",0.9,"-","Table R.16-8, susp.matter"]
[null,"Weight fraction organic carbon in susp.solids (Foc_susp)",0.1,"-","Table R.16-8, susp.matter"]
[null,"Volume fraction solids in sediment (Fsolid_sed)",0.2,"-","Table R.16-8, sediment"]
[null,"Volume fraction water in sediment (Fwater_sed)",0.8,"-","Table R.16-8, sediment"]
[null,"Weight fraction organic carbon in sediment solids (Foc_sed)",0.05,"-","Table R.16-8, sediment"]
[null,"Fraction of rainwater that infiltrates into soil (Finf_soil)",0.25,"-","Table R.16-18"]
[null,"Rate of wet precipitation (RAINrate)",{"$f":"700/1000/365","v":1.9178082191780822E-3},"m/d","Table R.16-18 (avg.annual precipitation 700 mm/y)"]
[null,"RAINrate_sec",{"$f":"RAINrate/24/3600","v":2.219685438863521E-8},"m/s","Conversion rain rate to m/s"]
[null,"Fraction runoff (Frunoff)",0.25,"-","Simplebox Table 2; volume fraction of precipitation running off"]
[null,"Erosion (erosion)",9.5100000000000009E-13,"m/s","Simplebox Table 2; erosion of soils"]
[null,"Residence time of water (time_res)",40,"d","Table R.16-18"]
[null,"Rate of advective downward transport of soil particles (SOLIDadv.soil)",6.34E-12,"m/d","Default R.16, pg.146"]
[null,"Solid phase diffusion coefficient in the soil compartment (SOLIDdiff.soil)",6.3699999999999997E-12,"m/d","Default R.16, pg.146"]
[null,"Partial mass-transfer coefficient at air side of the air-soil interface (Kasl_air)",{"$f":"0.00105*60*60*24","v":90.72},"m/d","Table R.16-19 (1.05E-3 m/sec)"]
[null,"Density wet soil (RHOsoil_wet)",{"$f":"(Fsolid_soil*RHOsolid)+(Fwater_soil*RHOwater)+(Fair_soil*RHOair)","v":1700.26},"kg/m3","Default R.16, calculated Eqn R.16-1"]
[null,"Density dry soil (RHOsoil_dry)",{"$f":"(Fsolid_soil*RHOsolid)+(Fair_soil*RHOair)","v":1500.26},"kg/m3","Default R.16, calculated Eqn R.16-1"]
[null,"Water content soil",{"$f":"Fwater_soil/(Fsolid_soil*RHOsolid/1000)","v":0.13333333333333333},"L/kg dw","Default, calculated"]
[null,"Density suspended matter (RHOsusp)",{"$f":"(Fsolid_susp*RHOsolid)+(Fwater_susp*RHOwater)","v":1150},"kg/m3","Default R.16, calculated Eqn R.16-1"]
[null,"Density sediment (RHOsed)",{"$f":"Fsolid_sed*RHOsolid+Fwater_sed*RHOwater","v":1300},"kg/m3","Default R.16, calculated Eqn R.16-1"]
[null,"Averaging time for Clocal soil (time)",30,"d","Default R.16, pg. 62, 127"]
[null,"Averaging time for crop uptake (timecrops)",180,"d","Default R.16, pg. 62, 127"]
[]
[]
[null,null,null,null,"Tool developed by ARCHE Consulting © 2017"]

{"sheet":"Calculations","index":4,"n_rows":82,"n_cols":5,"rows_kept":82,"cut":false,"hidden":false,"merged":[]}
[null,"FERTILIZER ENVIRONMENTAL EXPOSURE (FEE) TOOL"]
[null,"CALCULATIONS"]
[]
[null,"System properties","Value","Unit","Comments"]
[null,"Water solubility at 25°C",{"$f":"IF(SOL_M>0,SOL_M,SOL_D)","v":100},"mg/L","Select from input sheet"]
[null,"Henry coefficient (Henry)",{"$f":"IF(Henry_M>0,Henry_M,IF(Henry_D=0.000004,0.000004,IF(AND(MOLW_M>0,SOL_M>0,VP_M>0),(VP_M*MOLW_M/SOL_M))))","v":3.9999999999999998E-6},"Pa*m3/mol","Eqn R.16-4; calculated from mol.weight, solubility and vapour pressure if no Henry coefficient is provided"]
[null,"Partition coefficient solid-water in soil  (Kpsoil)",{"$f":"IF(Kpsoil_M>0,Kpsoil_M,IF(AND(Substance=\"-> Other\",Koc_M>0),(Koc_M*Foc_soil),Kpsoil_D))","v":2120},"L/kg","Eqn R.16-6; calculated from Koc if no manual/default Kpsoil input data is provided"]
[null,"Kpsoil (Kpsoil_category)",{"$f":"IF(Kpsoil<=100,Biodegradation!C7,IF(Kpsoil<=1000,Biodegradation!C8,IF(Kpsoil<=10000,Biodegradation!C9,IF(Kpsoil<=100000,Biodegradation!C10))))","v":"Kp 1000 - 10000"},null,"Category selected based on data in Kpsoil"]
[null,"Biodegradation in soil (DT50soil_category)",{"$f":"IF(Substance=\"-> Other\",DT50_bio_soil_M,DT50_bio_soil_D)","v":"Not biodegradable"},null,"Select from input sheet"]
[null,"Biodegradation in soil (DT50_soil)",{"$f":"IF(AND(Substance=\"-> Other\",Half_life_soil_M>0),Half_life_soil_M,IF(AND(Substance=\"-> Other\",Kpsoil_M=0),\"Provide manual input (DT50 or Kpsoil)\",VLOOKUP(Kpsoil_category,Biodegradation!C6:G10,MATCH(DT50soil_category,Biodegradation!C6:G6,FALSE),FALSE)))","v":1000000},"days","Lookup table"]
[null,"Biodegradation in water (DT50_water)",{"$f":"IF(AND(Substance=\"-> Other\",DT50bio_water_sed_M>0),DT50bio_water_sed_M,IF(Substance=\"-> Other\",\"Provide manual input\",VLOOKUP(Biodegradation!C11,Biodegradation!C6:G11,MATCH(DT50soil_category,Biodegradation!C6:G6,FALSE),FALSE)))","v":1000000},"days","Lookup table"]
[null,"Partition coefficient solid-water of susp. matter (Kpsusp)",{"$f":"IF(Kpsusp_M>0,Kpsusp_M,IF(AND(Substance=\"-> Other\",Koc_M>0),(Koc_M*Foc_susp),Kpsusp_D))","v":30246},"L/kg","Eqn R.16-6; calculated from Koc if no manual/default Kpsusp input data is provided"]
[null,"Kair_water",{"$f":"Henry/8.314/TEMP","v":1.6881269809115041E-9},"-","Eqn R.16-5"]
[null,"Ksoil_water",{"$f":"Fair_soil*Kair_water+Fwater_soil+Fsolid_soil*Kpsoil/1000*RHOsolid","v":3180.2000000003377},"m3/m3","Eqn R.16-7"]
[null,"Ksusp_water",{"$f":"Fwater_susp+Fsolid_susp*Kpsusp/1000*RHOsolid","v":7562.4000000000005},"m3/m3","Eqn R.16-7"]
[null,"Partial mass-transfer coefficient at soil side of the air-soil interface (Kasl_soil)",{"$f":"Veff_soil+Deff_soil/dp","v":1.5082675883591445E-7},"m/d","Eqn R.16-67"]
[null,"Substance dependent penetration depth (dp)",{"$f":"(Veff_soil+SQRT(POWER(Veff_soil,2)+Deff_soil*4*kbio_soil))/(2*kbio_soil)","v":0.21759701700592946},"m","Eqn R.16-68"]
[null,"Effective advection (with penetrating pore water)(Veff_soil)",{"$f":"FRw.soil*(RAINrate*Finf_soil/Fwater_soil)+FRs.soil*(SOLIDadv.soil/Fsolid_soil)","v":1.5077217055357198E-7},"m","Eqn R.16-69"]
[null,"Effective diffusion coefficient (Deff_soil)",{"$f":"FRa.soil*(DIFFgas*POWER(Fair_soil,1.5)/Fair_soil)+FRw.soil*(DIFFwater*POWER(Fwater_soil,1.5)/Fwater_soil)+FRs.soil*(SOLIDdiff.soil/Fsolid_soil)","v":1.1878247401198764E-11},"m2/d","Eqn R.16-70"]
[null,"Mass fraction of the substance in the water phase of soil (FRw.soil)",{"$f":"Fwater_soil/(Fair_soil*Kair_water+Fwater_soil+Fsolid_soil*Kpsoil*RHOsolid/1000)","v":6.2889126470026658E-5},"-","Eqn R.16-71"]
[null,"Mass fraction of the substance in the solid phase of soil (FRs.soil)",{"$f":"Fsolid_soil/(Fair_soil*Kair_water/(Kpsoil*RHOsolid/1000)+Fwater_soil/(Kpsoil*RHOsolid/1000)+Fsolid_soil)","v":0.99993711087342385},"-","Eqn R.16-72"]
[null,"Mass fraction of the substance in the air phase of soil (Fra.soil)",{"$f":"1-FRw.soil-FRs.soil","v":1.0613732115416497E-13},"-","Eqn R.16-73"]
[null,"Molecular diffusivity of the substance in the gas phase (DIFFgas)",{"$f":"IF(MOLW_M>0,(0.0000257*SQRT(18/(MOLW_M/1000))),(0.0000257*SQRT(18/(MOLW_D/1000))))","v":4.3252538207242828E-4},"m2/d","Eqn R.16-74"]
[null,"Molecular diffusivity of the substance in the water phase (DIFFwater)",{"$f":"IF(MOLW_M>0,(0.000000002*SQRT(32/(MOLW_M/1000))),(0.000000002*SQRT(32/(MOLW_D/1000))))","v":4.4879417076257157E-8},"m2/d","Eqn R.16-75"]
[]
[null,"Crop metal concentration",{"$f":"IF(Crop_conc_M<>\"\",Crop_conc_M,Crop_conc_D)","v":0},"g/t","Select from input sheet"]
[null,"Crop yield",{"$f":"IF(Crop_yield_M<>\"\",Crop_yield_M,Crop_yield_D)","v":0},"t/ha/y","Select from input sheet"]
[null,"Crop offtake",{"$f":"(Metal_conc*0.001)*Yield","v":0},"kg/ha/y"]
[null,"Pseudo-first order rate constant for volatilisation from soil (kvolat)",{"$f":"1/(((1/(Kasl_air*Kair_water/Ksoil_water))+(1/Kasl_soil))*DEPTHsoil)","v":2.4070498423609496E-10},"1/d","Eqn R.16-45"]
[null,"Pseudo-first order rate constant for leaching from top soil (kleach)",{"$f":"Finf_soil*RAINrate/(Ksoil_water*DEPTHsoil)","v":7.5380802275716865E-7},"1/d","Eqn R.16-46"]
[null,"Pseudo-first order rate constant for biodegradation in soil (kbio_soil)",{"$f":"LN(2)/DT50_soil","v":6.9314718055994524E-7},"1/d","Eqn R.16-13"]
[null,"First order rate constant for removal from top soil (ktotal)",{"$f":"kvolat+kleach+kbio_soil","v":1.44719590830135E-6},"1/d","Eqn R.16-44"]
[null,"Factor_1 removal soil within year 1 (F_1)",{"$f":"IF(Number_of_applications>1,1-EXP(-Number_of_applications*Time_between_applications*ktotal),1)","v":1},"1/d","Focus Steps 1-2 calc "]
[null,"Factor_2 removal soil within year 1 (F_2)",{"$f":"IF(Number_of_applications>1,1-EXP(-Time_between_applications*ktotal),1)","v":1},"1/d","Focus Steps 1-2 calc "]
[null,"Fraction accumulation in soil in one year (Facc)",{"$f":"EXP(-365*ktotal)","v":0.99947191298052973},"-","Eqn R.16-49"]
[null,"Correction factor runoff (Corr_runoff)",{"$f":"(DEPTHsoil_runoff/0.1)/(1-EXP(-DEPTHsoil_runoff/0.1))","v":1.1033311132253987},"-","Simplebox Eqn 111"]
[null,"Correction factor runoff_incorp (Corr_runoff_incorp)",{"$f":"(DEPTHsoil/0.1)/(1-EXP(-DEPTHsoil/0.1))","v":2.3130352854993315},null,"Simplebox Eqn 111"]
[null,"Correction factor runoff/depth (Corr_runoff_depth)",{"$f":"Corr_runoff/DEPTHsoil_runoff","v":55.166555661269932},"-","Simplebox Eqn 112"]
[null,"Correction factor runoff/depth (Corr_runoff_depth_soil_incorp)",{"$f":"Corr_runoff_incorp/DEPTHsoil","v":11.565176427496656},"-","Simplebox Eqn 112"]
[null,"Ksoil_water_runoff",{"$f":"(((RAINrate_sec*Frunoff/Ksoil_water)+erosion)*Corr_runoff_depth)*3600*24","v":1.2849835728155206E-5},"1/d","Simplebox Eqn 112"]
[null,"Ksoil_water_runoff_soil_incorp",{"$f":"(((RAINrate_sec*Frunoff/Ksoil_water)+erosion)*Corr_runoff_depth_soil_incorp)*3600*24","v":2.6938534675420753E-6},"1/d","Simplebox Eqn 112"]
[null,"Rate constant for removal from water-sediment phase (kbio_water_sed)",{"$f":"IF(Substance=\"-> Other\",(LN(2)/DT50bio_water_sed_M),(LN(2)/1000000))","v":6.9314718055994524E-7},"1/d","Modified Eqn R.16-13"]
[null,"Rate constant for residence time in water body (kres)",{"$f":"1/time_res","v":2.5000000000000001E-2},"1/d"]
[null,"First order rate constant for removal from water phase (ktotal_water)",{"$f":"kbio_water_sed+kdill","v":2.500069314718056E-2},"1/d","Modified Eqn R.16-44"]
[null,"Fraction accumulation in water_sediment in one year (Facc_water_sed)",{"$f":"EXP(-365*ktotal_water)","v":1.0888121956083936E-4},"-","Modified Eqn R.16-49"]
[]
[null,"Equivalent application rate, single (App_eq)",{"$f":"IF(Single_Multi=\"Multiple\",APPL_rate,APPL_rate_year)","v":0},"kg/ha","Application rate of element/substance in fertilizer, per application"]
[null,"Runoff percentage related to soil residue (Runoff_perc)",{"$f":"IF(Runoff_refined_RMM<>\"\",Runoff_refined_RMM,IF(Runoff_refined_soil_incorp<>\"\",Runoff_refined_soil_incorp,IF(Runoff_refined<>\"\",Runoff_refined,Runoff_D)))","v":3.8542077816643427E-2},"%","Select from input sheet including runoff reduction if applicable"]
[null,"Crop interception fraction (Fcrop_int)",{"$f":"IF(Crop_interception_M=\"\",0,Crop_interception_M/100)","v":0},"-","Select from input sheet"]
[null,"Drift percentage (Drift_perc)",{"$f":"IF(Drift_RMM<>\"\",Drift_RMM,IF(Drift_refined=\"\",Drift_D,Drift_refined))","v":0},"%","Select from input sheet"]
[null,"Volatilization percentage (Vol_perc)",{"$f":"IF(Substance=\"-> Other\",VLOOKUP(Vol_M,'SpERC details'!F4:G10,2,FALSE),Vol_D)","v":0},"%","Select from input sheet or lookup table"]
[null,"Equivalent application rate to soil, all applications (App_eq_soil)",{"$f":"App_eq*(F_1/F_2)","v":0},"kg/ha","App_eq_soil = App_eq, corrected for removal from soil between applications"]
[null,"Final input to soil, all applications (App_soil)",{"$f":"App_eq*((100-Runoff_perc)/100)*(F_1/F_2)","v":0},"kg/ha","App_soil = App_eq - runoff, corrected for runoff and removal from soil between applications"]
[null,"Total input to soil, taking into account crop offtake (Input_soil)",{"$f":"IF(App_soil-Crop_offtake>0,App_soil-Crop_offtake,0)","v":0},"kg/ha"]
[]
[null,"Concentration in soil after 1st year application excluding crop offtake (Csoil1_no offtake)",{"$f":"(App_soil*100)/(DEPTHsoil*RHOsoil_dry)","v":0},"mg/kg dw","Similar to Eqn R.16-48"]
[null,"Concentration in soil after 1st year application including crop offtake (Csoil1)",{"$f":"(Input_soil*100)/(DEPTHsoil*RHOsoil_dry)","v":0},"mg/kg dw","Similar to Eqn R.16-48"]
[null,"Concentration in surface water after 1st year application (Csurfacewater1)",{"$f":"MAX(Conc_sw!L6:L106)","v":0},"µg/L","Modified Eqn R.16-29"]
[]
[null,"Concentration in soil after 10 years (Csoil10_no offtake)",{"$f":"Csoil1_no_offtake*(1+POWER(Facc,1)+POWER(Facc,2)+POWER(Facc,3)+POWER(Facc,4)+POWER(Facc,5)+POWER(Facc,6)+POWER(Facc,7)+POWER(Facc,8)+POWER(Facc,9))","v":0},"mg/kg dw","Eqn R.16-50"]
[null,"Concentration in soil after 10 years (Csoil10)",{"$f":"Csoil1*(1+POWER(Facc,1)+POWER(Facc,2)+POWER(Facc,3)+POWER(Facc,4)+POWER(Facc,5)+POWER(Facc,6)+POWER(Facc,7)+POWER(Facc,8)+POWER(Facc,9))","v":0},"mg/kg dw","Eqn R.16-50"]
[null,"Concentration in surface water after 10th application (Csurfacewater10)",{"$f":"Csurfacewater1*(1+POWER(Facc_water_sed,1)+POWER(Facc_water_sed,2)+POWER(Facc_water_sed,3)+POWER(Facc_water_sed,4)+POWER(Facc_water_sed,5)+POWER(Facc_water_sed,6)+POWER(Facc_water_sed,7)+POWER(Facc_water_sed,8)+POWER(Facc_water_sed,9))","v":0},"µg/L","Modified Eqn R.16-50"]
[]
[null,"RCR regional soil",{"$f":"PEC_regional_soil/PNEC_soil","v":0.2153846153846154},"-","Select from output sheet"]
[null,"RCR regional freshwater",{"$f":"PECregional_water/PNEC_water","v":0.37179487179487181},"-","Select from output sheet"]
[null,"RCR regional sediment",{"$f":"PEC_regional_sediment/PNEC_sediment","v":0.77586206896551724},"-","Select from output sheet"]
[null,"RCR crop offtake",{"$f":"IF(Crop_offtake<>0,((Crop_offtake*100)/(DEPTHsoil*RHOsoil_dry))/PNEC_soil,\"\")","v":""}]
[null,"Target RCR local soil",{"$f":"IF(Crop_offtake<>0,Target_RCR-RCR_regional_soil+RCR_crop_offtake,Target_RCR-RCR_regional_soil)","v":0.68461538461538463},"-"]
[null,"Target RCR local freshwater",{"$f":"Target_RCR-RCR_regional_freshwater","v":0.52820512820512822},"-"]
[null,"Target RCR local sediment",{"$f":"Target_RCR-RCR_regional_sediment","v":0.12413793103448278},"-"]
[null,"Max Clocal soil",{"$f":"PNEC_soil*Target_RCR_local_soil","v":44.5},"mg/kg dw"]
[null,"Max Clocal freshwater",{"$f":"PNEC_water*Target_RCR_local_freshwater","v":4.12},"µg/L"]
[null,"Max Clocal sediment",{"$f":"PNEC_sediment*Target_RCR_local_sediment","v":10.800000000000002},"mg/kg"]
[null,"Max application rate soil 1 year",{"$f":"IF(Csoil_1_30>0,APPL_rate_year*(Max_Clocal_soil/(1/(ktotal*time)*Csoil1_no_offtake*(1-EXP(-ktotal*time)))),1000)","v":1000},"kg/ha/year"]
[null,"Max application rate freshwater 1 year",{"$f":"IF(Cwater_1_30>0,APPL_rate_year*(Max_Clocal_freshwater/Cwater_1_30),1000)","v":1000},"kg/ha/year"]
[null,"Max application rate sediment 1 year",{"$f":"IF(Csediment_1_30>0,APPL_rate_year*(Max_Clocal_sediment/Csediment_1_30),1000)","v":1000},"kg/ha/year"]
[null,"Max application rate soil 10 year",{"$f":"IF(Csoil_10_30>0,APPL_rate_year*(Max_Clocal_soil/(1/(ktotal*time)*Csoil10_no_offtake*(1-EXP(-ktotal*time)))),1000)","v":1000},"kg/ha/year, 10 years"]
[null,"Max application rate freshwater 10 year",{"$f":"IF(Cwater_10_30>0,APPL_rate_year*(Max_Clocal_freshwater/Cwater_10_30),1000)","v":1000},"kg/ha/year, 10 years"]
[null,"Max application rate sediment 10 year",{"$f":"IF(Csediment_10_30>0,APPL_rate_year*(Max_Clocal_sediment/Csediment_10_30),1000)","v":1000},"kg/ha/year, 10 years"]
[]
[]
[null,null,null,null,"Tool developed by ARCHE Consulting © 2017"]

{"sheet":"Conc_sw","index":5,"n_rows":371,"n_cols":12,"rows_kept":371,"cut":false,"hidden":true,"merged":[]}
[null,"FERTILIZER ENVIRONMENTAL EXPOSURE (FEE) TOOL"]
[null,"EXPOSURE SURFACE WATER"]
[]
[null,"Input parameters",null,null,null,null,"Conc surface water calculations"]
[null,"Input runoff [mg/m2]","Input drift [mg/m2]","Total input [µg/L]","Csurface water [µg/L]",null,"Day no","Input runoff [mg/m2]","Input drift [mg/m2]","Total input [µg/L]","Total input incl removal [µg/L]","Csurface water [µg/L]"]
[null,{"$f":"App_eq_soil*Runoff_perc*RATIO","v":0},{"$f":"App_eq*Drift_perc","v":0},{"$f":"(Input_runoff+Input_drift)/DEPTHwater","v":0},{"$f":"IF((Input_sw)/(1+Kpsusp*SUSPwater*0.000001)<(SOL*1000),(Input_sw)/(1+Kpsusp*SUSPwater*0.000001),(SOL*1000))","v":0},null,0,{"$f":"IF(G6=((Time_between_applications*(Number_of_applications-1))+4),Input_runoff,0)","v":0},{"$f":"Input_drift","v":0},{"$f":"(H6+I6)/DEPTHwater","v":0},{"$f":"J6*EXP(-ktotal_water*G6)","v":0},{"$f":"(K6)/(1+Kpsusp*SUSPwater*0.000001)","v":0}]
[null,null,null,null,null,null,1,0,{"$f":"IF(Single_Multi=\"Single\",0,IF(AND(MOD(G7/Time_between_applications,1)=0,OR((Conc_sw!G7<Conc_sw!$C$10),(Conc_sw!G7=Conc_sw!$C$10))),Input_drift,0))","v":0},0,{"$f":"(J7+K6)*EXP(-ktotal_water*$G$7)","v":0},0]
[null,null,null,null,null,null,2,0,{"$f":"IF(Single_Multi=\"Single\",0,IF(AND(MOD(G8/Time_between_applications,1)=0,OR((Conc_sw!G8<Conc_sw!$C$10),(Conc_sw!G8=Conc_sw!$C$10))),Input_drift,0))","v":0},0,0,0]
[null,null,null,null,null,null,3,0,{"$f":"IF(Single_Multi=\"Single\",0,IF(AND(MOD(G9/Time_between_applications,1)=0,OR((Conc_sw!G9<Conc_sw!$C$10),(Conc_sw!G9=Conc_sw!$C$10))),Input_drift,0))","v":0},0,0,0]
[null,"Maximum days",{"$f":"Time_between_applications*(Number_of_applications-1)","v":0},null,null,null,4,0,{"$f":"IF(Single_Multi=\"Single\",0,IF(AND(MOD(G10/Time_between_applications,1)=0,OR((Conc_sw!G10<Conc_sw!$C$10),(Conc_sw!G10=Conc_sw!$C$10))),Input_drift,0))","v":0},0,0,0]
[null,null,null,null,null,null,5,0,{"$f":"IF(Single_Multi=\"Single\",0,IF(AND(MOD(G11/Time_between_applications,1)=0,OR((Conc_sw!G11<Conc_sw!$C$10),(Conc_sw!G11=Conc_sw!$C$10))),Input_drift,0))","v":0},0,0,0]
[null,null,null,null,null,null,6,0,{"$f":"IF(Single_Multi=\"Single\",0,IF(AND(MOD(G12/Time_between_applications,1)=0,OR((Conc_sw!G12<Conc_sw!$C$10),(Conc_sw!G12=Conc_sw!$C$10))),Input_drift,0))","v":0},0,0,0]
[null,null,null,null,null,null,7,0,{"$f":"IF(Single_Multi=\"Single\",0,IF(AND(MOD(G13/Time_between_applications,1)=0,OR((Conc_sw!G13<Conc_sw!$C$10),(Conc_sw!G13=Conc_sw!$C$10))),Input_drift,0))","v":0},0,0,0]
[null,null,null,null,null,null,8,0,{"$f":"IF(Single_Multi=\"Single\",0,IF(AND(MOD(G14/Time_between_applications,1)=0,OR((Conc_sw!G14<Conc_sw!$C$10),(Conc_sw!G14=Conc_sw!$C$10))),Input_drift,0))","v":0},0,0,0]
[null,null,null,null,null,null,9,0,{"$f":"IF(Single_Multi=\"Single\",0,IF(AND(MOD(G15/Time_between_applications,1)=0,OR((Conc_sw!G15<Conc_sw!$C$10),(Conc_sw!G15=Conc_sw!$C$10))),Input_drift,0))","v":0},0,0,0]
[null,null,null,null,null,null,10,0,{"$f":"IF(Single_Multi=\"Single\",0,IF(AND(MOD(G16/Time_between_applications,1)=0,OR((Conc_sw!G16<Conc_sw!$C$10),(Conc_sw!G16=Conc_sw!$C$10))),Input_drift,0))","v":0},0,0,0]
[null,null,null,null,null,null,11,0,{"$f":"IF(Single_Multi=\"Single\",0,IF(AND(MOD(G17/Time_between_applications,1)=0,OR((Conc_sw!G17<Conc_sw!$C$10),(Conc_sw!G17=Conc_sw!$C$10))),Input_drift,0))","v":0},0,0,0]
[null,null,null,null,null,null,12,0,{"$f":"IF(Single_Multi=\"Single\",0,IF(AND(MOD(G18/Time_between_applications,1)=0,OR((Conc_sw!G18<Conc_sw!$C$10),(Conc_sw!G18=Conc_sw!$C$10))),Input_drift,0))","v":0},0,0,0]
[null,null,null,null,null,null,13,0,{"$f":"IF(Single_Multi=\"Single\",0,IF(AND(MOD(G19/Time_between_applications,1)=0,OR((Conc_sw!G19<Conc_sw!$C$10),(Conc_sw!G19=Conc_sw!$C$10))),Input_drift,0))","v":0},0,0,0]
[null,null,null,null,null,null,14,0,{"$f":"IF(Single_Multi=\"Single\",0,IF(AND(MOD(G20/Time_between_applications,1)=0,OR((Conc_sw!G20<Conc_sw!$C$10),(Conc_sw!G20=Conc_sw!$C$10))),Input_drift,0))","v":0},0,0,0]
[null,null,null,null,null,null,15,0,{"$f":"IF(Single_Multi=\"Single\",0,IF(AND(MOD(G21/Time_between_applications,1)=0,OR((Conc_sw!G21<Conc_sw!$C$10),(Conc_sw!G21=Conc_sw!$C$10))),Input_drift,0))","v":0},0,0,0]
[null,null,null,null,null,null,16,0,{"$f":"IF(Single_Multi=\"Single\",0,IF(AND(MOD(G22/Time_between_applications,1)=0,OR((Conc_sw!G22<Conc_sw!$C$10),(Conc_sw!G22=Conc_sw!$C$10))),Input_drift,0))","v":0},0,0,0]
[null,null,null,null,null,null,17,0,{"$f":"IF(Single_Multi=\"Single\",0,IF(AND(MOD(G23/Time_between_applications,1)=0,OR((Conc_sw!G23<Conc_sw!$C$10),(Conc_sw!G23=Conc_sw!$C$10))),Input_drift,0))","v":0},0,0,0]
[null,null,null,null,null,null,18,0,{"$f":"IF(Single_Multi=\"Single\",0,IF(AND(MOD(G24/Time_between_applications,1)=0,OR((Conc_sw!G24<Conc_sw!$C$10),(Conc_sw!G24=Conc_sw!$C$10))),Input_drift,0))","v":0},0,0,0]
[null,null,null,null,null,null,19,0,{"$f":"IF(Single_Multi=\"Single\",0,IF(AND(MOD(G25/Time_between_applications,1)=0,OR((Conc_sw!G25<Conc_sw!$C$10),(Conc_sw!G25=Conc_sw!$C$10))),Input_drift,0))","v":0},0,0,0]
[null,null,null,null,null,null,20,0,{"$f":"IF(Single_Multi=\"Single\",0,IF(AND(MOD(G26/Time_between_applications,1)=0,OR((Conc_sw!G26<Conc_sw!$C$10),(Conc_sw!G26=Conc_sw!$C$10))),Input_drift,0))","v":0},0,0,0]
[null,null,null,null,null,null,21,0,{"$f":"IF(Single_Multi=\"Single\",0,IF(AND(MOD(G27/Time_between_applications,1)=0,OR((Conc_sw!G27<Conc_sw!$C$10),(Conc_sw!G27=Conc_sw!$C$10))),Input_drift,0))","v":0},0,0,0]
[null,null,null,null,null,null,22,0,{"$f":"IF(Single_Multi=\"Single\",0,IF(AND(MOD(G28/Time_between_applications,1)=0,OR((Conc_sw!G28<Conc_sw!$C$10),(Conc_sw!G28=Conc_sw!$C$10))),Input_drift,0))","v":0},0,0,0]
[null,null,null,null,null,null,23,0,{"$f":"IF(Single_Multi=\"Single\",0,IF(AND(MOD(G29/Time_between_applications,1)=0,OR((Conc_sw!G29<Conc_sw!$C$10),(Conc_sw!G29=Conc_sw!$C$10))),Input_drift,0))","v":0},0,0,0]
[null,null,null,null,null,null,24,0,{"$f":"IF(Single_Multi=\"Single\",0,IF(AND(MOD(G30/Time_between_applications,1)=0,OR((Conc_sw!G30<Conc_sw!$C$10),(Conc_sw!G30=Conc_sw!$C$10))),Input_drift,0))","v":0},0,0,0]
[null,null,null,null,null,null,25,0,{"$f":"IF(Single_Multi=\"Single\",0,IF(AND(MOD(G31/Time_between_applications,1)=0,OR((Conc_sw!G31<Conc_sw!$C$10),(Conc_sw!G31=Conc_sw!$C$10))),Input_drift,0))","v":0},0,0,0]
[null,null,null,null,null,null,26,0,{"$f":"IF(Single_Multi=\"Single\",0,IF(AND(MOD(G32/Time_between_applications,1)=0,OR((Conc_sw!G32<Conc_sw!$C$10),(Conc_sw!G32=Conc_sw!$C$10))),Input_drift,0))","v":0},0,0,0]
[null,null,null,null,null,null,27,0,{"$f":"IF(Single_Multi=\"Single\",0,IF(AND(MOD(G33/Time_between_applications,1)=0,OR((Conc_sw!G33<Conc_sw!$C$10),(Conc_sw!G33=Conc_sw!$C$10))),Input_drift,0))","v":0},0,0,0]
[null,null,null,null,null,null,28,0,{"$f":"IF(Single_Multi=\"Single\",0,IF(AND(MOD(G34/Time_between_applications,1)=0,OR((Conc_sw!G34<Conc_sw!$C$10),(Conc_sw!G34=Conc_sw!$C$10))),Input_drift,0))","v":0},0,0,0]
[null,null,null,null,null,null,29,0,{"$f":"IF(Single_Multi=\"Single\",0,IF(AND(MOD(G35/Time_between_applications,1)=0,OR((Conc_sw!G35<Conc_sw!$C$10),(Conc_sw!G35=Conc_sw!$C$10))),Input_drift,0))","v":0},0,0,0]
[null,null,null,null,null,null,30,0,{"$f":"IF(Single_Multi=\"Single\",0,IF(AND(MOD(G36/Time_between_applications,1)=0,OR((Conc_sw!G36<Conc_sw!$C$10),(Conc_sw!G36=Conc_sw!$C$10))),Input_drift,0))","v":0},0,0,0]
[null,null,null,null,null,null,31,0,{"$f":"IF(Single_Multi=\"Single\",0,IF(AND(MOD(G37/Time_between_applications,1)=0,OR((Conc_sw!G37<Conc_sw!$C$10),(Conc_sw!G37=Conc_sw!$C$10))),Input_drift,0))","v":0},0,0,0]
[null,null,null,null,null,null,32,{"$f":"IF(G38=((Time_between_applications*(Number_of_applications-1))+4),Input_runoff,0)","v":0},{"$f":"IF(Single_Multi=\"Single\",0,IF(AND(MOD(G38/Time_between_applications,1)=0,OR((Conc_sw!G38<Conc_sw!$C$10),(Conc_sw!G38=Conc_sw!$C$10))),Input_drift,0))","v":0},{"$f":"(H38+I38)/DEPTHwater","v":0},0,{"$f":"(K38)/(1+Kpsusp*SUSPwater*0.000001)","v":0}]
[null,null,null,null,null,null,33,0,{"$f":"IF(Single_Multi=\"Single\",0,IF(AND(MOD(G39/Time_between_applications,1)=0,OR((Conc_sw!G39<Conc_sw!$C$10),(Conc_sw!G39=Conc_sw!$C$10))),Input_drift,0))","v":0},0,{"$f":"(J39+K38)*EXP(-ktotal_water*$G$7)","v":0},0]
[null,null,null,null,null,null,34,0,{"$f":"IF(Single_Multi=\"Single\",0,IF(AND(MOD(G40/Time_between_applications,1)=0,OR((Conc_sw!G40<Conc_sw!$C$10),(Conc_sw!G40=Conc_sw!$C$10))),Input_drift,0))","v":0},0,0,0]
[null,null,null,null,null,null,35,0,{"$f":"IF(Single_Multi=\"Single\",0,IF(AND(MOD(G41/Time_between_applications,1)=0,OR((Conc_sw!G41<Conc_sw!$C$10),(Conc_sw!G41=Conc_sw!$C$10))),Input_drift,0))","v":0},0,0,0]
[null,null,null,null,null,null,36,0,{"$f":"IF(Single_Multi=\"Single\",0,IF(AND(MOD(G42/Time_between_applications,1)=0,OR((Conc_sw!G42<Conc_sw!$C$10),(Conc_sw!G42=Conc_sw!$C$10))),Input_drift,0))","v":0},0,0,0]
[null,null,null,null,null,null,37,0,{"$f":"IF(Single_Multi=\"Single\",0,IF(AND(MOD(G43/Time_between_applications,1)=0,OR((Conc_sw!G43<Conc_sw!$C$10),(Conc_sw!G43=Conc_sw!$C$10))),Input_drift,0))","v":0},0,0,0]
[null,null,null,null,null,null,38,0,{"$f":"IF(Single_Multi=\"Single\",0,IF(AND(MOD(G44/Time_between_applications,1)=0,OR((Conc_sw!G44<Conc_sw!$C$10),(Conc_sw!G44=Conc_sw!$C$10))),Input_drift,0))","v":0},0,0,0]
[null,null,null,null,null,null,39,0,{"$f":"IF(Single_Multi=\"Single\",0,IF(AND(MOD(G45/Time_between_applications,1)=0,OR((Conc_sw!G45<Conc_sw!$C$10),(Conc_sw!G45=Conc_sw!$C$10))),Input_drift,0))","v":0},0,0,0]
[null,null,null,null,null,null,40,0,{"$f":"IF(Single_Multi=\"Single\",0,IF(AND(MOD(G46/Time_between_applications,1)=0,OR((Conc_sw!G46<Conc_sw!$C$10),(Conc_sw!G46=Conc_sw!$C$10))),Input_drift,0))","v":0},0,0,0]
[null,null,null,null,null,null,41,0,{"$f":"IF(Single_Multi=\"Single\",0,IF(AND(MOD(G47/Time_between_applications,1)=0,OR((Conc_sw!G47<Conc_sw!$C$10),(Conc_sw!G47=Conc_sw!$C$10))),Input_drift,0))","v":0},0,0,0]
[null,null,null,null,null,null,42,0,{"$f":"IF(Single_Multi=\"Single\",0,IF(AND(MOD(G48/Time_between_applications,1)=0,OR((Conc_sw!G48<Conc_sw!$C$10),(Conc_sw!G48=Conc_sw!$C$10))),Input_drift,0))","v":0},0,0,0]
[null,null,null,null,null,null,43,0,{"$f":"IF(Single_Multi=\"Single\",0,IF(AND(MOD(G49/Time_between_applications,1)=0,OR((Conc_sw!G49<Conc_sw!$C$10),(Conc_sw!G49=Conc_sw!$C$10))),Input_drift,0))","v":0},0,0,0]
[null,null,null,null,null,null,44,0,{"$f":"IF(Single_Multi=\"Single\",0,IF(AND(MOD(G50/Time_between_applications,1)=0,OR((Conc_sw!G50<Conc_sw!$C$10),(Conc_sw!G50=Conc_sw!$C$10))),Input_drift,0))","v":0},0,0,0]
[null,null,null,null,null,null,45,0,{"$f":"IF(Single_Multi=\"Single\",0,IF(AND(MOD(G51/Time_between_applications,1)=0,OR((Conc_sw!G51<Conc_sw!$C$10),(Conc_sw!G51=Conc_sw!$C$10))),Input_drift,0))","v":0},0,0,0]
[null,null,null,null,null,null,46,0,{"$f":"IF(Single_Multi=\"Single\",0,IF(AND(MOD(G52/Time_between_applications,1)=0,OR((Conc_sw!G52<Conc_sw!$C$10),(Conc_sw!G52=Conc_sw!$C$10))),Input_drift,0))","v":0},0,0,0]
[null,null,null,null,null,null,47,0,{"$f":"IF(Single_Multi=\"Single\",0,IF(AND(MOD(G53/Time_between_applications,1)=0,OR((Conc_sw!G53<Conc_sw!$C$10),(Conc_sw!G53=Conc_sw!$C$10))),Input_drift,0))","v":0},0,0,0]
[null,null,null,null,null,null,48,0,{"$f":"IF(Single_Multi=\"Single\",0,IF(AND(MOD(G54/Time_between_applications,1)=0,OR((Conc_sw!G54<Conc_sw!$C$10),(Conc_sw!G54=Conc_sw!$C$10))),Input_drift,0))","v":0},0,0,0]
[null,null,null,null,null,null,49,0,{"$f":"IF(Single_Multi=\"Single\",0,IF(AND(MOD(G55/Time_between_applications,1)=0,OR((Conc_sw!G55<Conc_sw!$C$10),(Conc_sw!G55=Conc_sw!$C$10))),Input_drift,0))","v":0},0,0,0]
[null,null,null,null,null,null,50,0,{"$f":"IF(Single_Multi=\"Single\",0,IF(AND(MOD(G56/Time_between_applications,1)=0,OR((Conc_sw!G56<Conc_sw!$C$10),(Conc_sw!G56=Conc_sw!$C$10))),Input_drift,0))","v":0},0,0,0]
[null,null,null,null,null,null,51,0,{"$f":"IF(Single_Multi=\"Single\",0,IF(AND(MOD(G57/Time_between_applications,1)=0,OR((Conc_sw!G57<Conc_sw!$C$10),(Conc_sw!G57=Conc_sw!$C$10))),Input_drift,0))","v":0},0,0,0]
[null,null,null,null,null,null,52,0,{"$f":"IF(Single_Multi=\"Single\",0,IF(AND(MOD(G58/Time_between_applications,1)=0,OR((Conc_sw!G58<Conc_sw!$C$10),(Conc_sw!G58=Conc_sw!$C$10))),Input_drift,0))","v":0},0,0,0]
[null,null,null,null,null,null,53,0,{"$f":"IF(Single_Multi=\"Single\",0,IF(AND(MOD(G59/Time_between_applications,1)=0,OR((Conc_sw!G59<Conc_sw!$C$10),(Conc_sw!G59=Conc_sw!$C$10))),Input_drift,0))","v":0},0,0,0]
[null,null,null,null,null,null,54,0,{"$f":"IF(Single_Multi=\"Single\",0,IF(AND(MOD(G60/Time_between_applications,1)=0,OR((Conc_sw!G60<Conc_sw!$C$10),(Conc_sw!G60=Conc_sw!$C$10))),Input_drift,0))","v":0},0,0,0]
[null,null,null,null,null,null,55,0,{"$f":"IF(Single_Multi=\"Single\",0,IF(AND(MOD(G61/Time_between_applications,1)=0,OR((Conc_sw!G61<Conc_sw!$C$10),(Conc_sw!G61=Conc_sw!$C$10))),Input_drift,0))","v":0},0,0,0]
[null,null,null,null,null,null,56,0,{"$f":"IF(Single_Multi=\"Single\",0,IF(AND(MOD(G62/Time_between_applications,1)=0,OR((Conc_sw!G62<Conc_sw!$C$10),(Conc_sw!G62=Conc_sw!$C$10))),Input_drift,0))","v":0},0,0,0]
[null,null,null,null,null,null,57,0,{"$f":"IF(Single_Multi=\"Single\",0,IF(AND(MOD(G63/Time_between_applications,1)=0,OR((Conc_sw!G63<Conc_sw!$C$10),(Conc_sw!G63=Conc_sw!$C$10))),Input_drift,0))","v":0},0,0,0]
[null,null,null,null,null,null,58,0,{"$f":"IF(Single_Multi=\"Single\",0,IF(AND(MOD(G64/Time_between_applications,1)=0,OR((Conc_sw!G64<Conc_sw!$C$10),(Conc_sw!G64=Conc_sw!$C$10))),Input_drift,0))","v":0},0,0,0]
[null,null,null,null,null,null,59,0,{"$f":"IF(Single_Multi=\"Single\",0,IF(AND(MOD(G65/Time_between_applications,1)=0,OR((Conc_sw!G65<Conc_sw!$C$10),(Conc_sw!G65=Conc_sw!$C$10))),Input_drift,0))","v":0},0,0,0]
[null,null,null,null,null,null,60,0,{"$f":"IF(Single_Multi=\"Single\",0,IF(AND(MOD(G66/Time_between_applications,1)=0,OR((Conc_sw!G66<Conc_sw!$C$10),(Conc_sw!G66=Conc_sw!$C$10))),Input_drift,0))","v":0},0,0,0]
[null,null,null,null,null,null,61,0,{"$f":"IF(Single_Multi=\"Single\",0,IF(AND(MOD(G67/Time_between_applications,1)=0,OR((Conc_sw!G67<Conc_sw!$C$10),(Conc_sw!G67=Conc_sw!$C$10))),Input_drift,0))","v":0},0,0,0]
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[null,null,null,null,null,null,346,0,{"$f":"IF(Single_Multi=\"Single\",0,IF(AND(MOD(G352/Time_between_applications,1)=0,OR((Conc_sw!G352<Conc_sw!$C$10),(Conc_sw!G352=Conc_sw!$C$10))),Input_drift,0))","v":0},0,0,0]
[null,null,null,null,null,null,347,0,{"$f":"IF(Single_Multi=\"Single\",0,IF(AND(MOD(G353/Time_between_applications,1)=0,OR((Conc_sw!G353<Conc_sw!$C$10),(Conc_sw!G353=Conc_sw!$C$10))),Input_drift,0))","v":0},0,0,0]
[null,null,null,null,null,null,348,0,{"$f":"IF(Single_Multi=\"Single\",0,IF(AND(MOD(G354/Time_between_applications,1)=0,OR((Conc_sw!G354<Conc_sw!$C$10),(Conc_sw!G354=Conc_sw!$C$10))),Input_drift,0))","v":0},0,0,0]
[null,null,null,null,null,null,349,0,{"$f":"IF(Single_Multi=\"Single\",0,IF(AND(MOD(G355/Time_between_applications,1)=0,OR((Conc_sw!G355<Conc_sw!$C$10),(Conc_sw!G355=Conc_sw!$C$10))),Input_drift,0))","v":0},0,0,0]
[null,null,null,null,null,null,350,0,{"$f":"IF(Single_Multi=\"Single\",0,IF(AND(MOD(G356/Time_between_applications,1)=0,OR((Conc_sw!G356<Conc_sw!$C$10),(Conc_sw!G356=Conc_sw!$C$10))),Input_drift,0))","v":0},0,0,0]
[null,null,null,null,null,null,351,0,{"$f":"IF(Single_Multi=\"Single\",0,IF(AND(MOD(G357/Time_between_applications,1)=0,OR((Conc_sw!G357<Conc_sw!$C$10),(Conc_sw!G357=Conc_sw!$C$10))),Input_drift,0))","v":0},0,0,0]
[null,null,null,null,null,null,352,0,{"$f":"IF(Single_Multi=\"Single\",0,IF(AND(MOD(G358/Time_between_applications,1)=0,OR((Conc_sw!G358<Conc_sw!$C$10),(Conc_sw!G358=Conc_sw!$C$10))),Input_drift,0))","v":0},0,0,0]
[null,null,null,null,null,null,353,0,{"$f":"IF(Single_Multi=\"Single\",0,IF(AND(MOD(G359/Time_between_applications,1)=0,OR((Conc_sw!G359<Conc_sw!$C$10),(Conc_sw!G359=Conc_sw!$C$10))),Input_drift,0))","v":0},0,0,0]
[null,null,null,null,null,null,354,0,{"$f":"IF(Single_Multi=\"Single\",0,IF(AND(MOD(G360/Time_between_applications,1)=0,OR((Conc_sw!G360<Conc_sw!$C$10),(Conc_sw!G360=Conc_sw!$C$10))),Input_drift,0))","v":0},0,0,0]
[null,null,null,null,null,null,355,0,{"$f":"IF(Single_Multi=\"Single\",0,IF(AND(MOD(G361/Time_between_applications,1)=0,OR((Conc_sw!G361<Conc_sw!$C$10),(Conc_sw!G361=Conc_sw!$C$10))),Input_drift,0))","v":0},0,0,0]
[null,null,null,null,null,null,356,0,{"$f":"IF(Single_Multi=\"Single\",0,IF(AND(MOD(G362/Time_between_applications,1)=0,OR((Conc_sw!G362<Conc_sw!$C$10),(Conc_sw!G362=Conc_sw!$C$10))),Input_drift,0))","v":0},0,0,0]
[null,null,null,null,null,null,357,{"$f":"IF(G363=((Time_between_applications*(Number_of_applications-1))+4),Input_runoff,0)","v":0},{"$f":"IF(Single_Multi=\"Single\",0,IF(AND(MOD(G363/Time_between_applications,1)=0,OR((Conc_sw!G363<Conc_sw!$C$10),(Conc_sw!G363=Conc_sw!$C$10))),Input_drift,0))","v":0},{"$f":"(H363+I363)/DEPTHwater","v":0},{"$f":"(J363+K362)*EXP(-ktotal_water*$G$7)","v":0},{"$f":"(K363)/(1+Kpsusp*SUSPwater*0.000001)","v":0}]
[null,null,null,null,null,null,358,0,{"$f":"IF(Single_Multi=\"Single\",0,IF(AND(MOD(G364/Time_between_applications,1)=0,OR((Conc_sw!G364<Conc_sw!$C$10),(Conc_sw!G364=Conc_sw!$C$10))),Input_drift,0))","v":0},0,0,0]
[null,null,null,null,null,null,359,0,{"$f":"IF(Single_Multi=\"Single\",0,IF(AND(MOD(G365/Time_between_applications,1)=0,OR((Conc_sw!G365<Conc_sw!$C$10),(Conc_sw!G365=Conc_sw!$C$10))),Input_drift,0))","v":0},0,0,0]
[null,null,null,null,null,null,360,0,{"$f":"IF(Single_Multi=\"Single\",0,IF(AND(MOD(G366/Time_between_applications,1)=0,OR((Conc_sw!G366<Conc_sw!$C$10),(Conc_sw!G366=Conc_sw!$C$10))),Input_drift,0))","v":0},0,0,0]
[null,null,null,null,null,null,361,0,{"$f":"IF(Single_Multi=\"Single\",0,IF(AND(MOD(G367/Time_between_applications,1)=0,OR((Conc_sw!G367<Conc_sw!$C$10),(Conc_sw!G367=Conc_sw!$C$10))),Input_drift,0))","v":0},0,0,0]
[null,null,null,null,null,null,362,0,{"$f":"IF(Single_Multi=\"Single\",0,IF(AND(MOD(G368/Time_between_applications,1)=0,OR((Conc_sw!G368<Conc_sw!$C$10),(Conc_sw!G368=Conc_sw!$C$10))),Input_drift,0))","v":0},0,0,0]
[null,null,null,null,null,null,363,0,{"$f":"IF(Single_Multi=\"Single\",0,IF(AND(MOD(G369/Time_between_applications,1)=0,OR((Conc_sw!G369<Conc_sw!$C$10),(Conc_sw!G369=Conc_sw!$C$10))),Input_drift,0))","v":0},0,0,0]
[null,null,null,null,null,null,364,0,{"$f":"IF(Single_Multi=\"Single\",0,IF(AND(MOD(G370/Time_between_applications,1)=0,OR((Conc_sw!G370<Conc_sw!$C$10),(Conc_sw!G370=Conc_sw!$C$10))),Input_drift,0))","v":0},0,0,0]
[null,null,null,null,null,null,365,0,{"$f":"IF(Single_Multi=\"Single\",0,IF(AND(MOD(G371/Time_between_applications,1)=0,OR((Conc_sw!G371<Conc_sw!$C$10),(Conc_sw!G371=Conc_sw!$C$10))),Input_drift,0))","v":0},0,0,0]

{"sheet":"Crop parameters","index":6,"n_rows":46,"n_cols":14,"rows_kept":46,"cut":false,"hidden":false,"merged":[[3,4,3,6],[6,4,6,6],[38,4,38,6],[3,7,3,9],[38,10,38,11],[3,10,3,13],[4,10,5,10],[4,11,5,11],[4,12,5,12],[4,13,5,13]]}
[null,"FERTILIZER ENVIRONMENTAL EXPOSURE (FEE) TOOL"]
[null,"CROP PARAMETERS"]
[]
[null,null,null,null,"Micronutrient concentration **",null,null,"Crop Yield (ww) ***",null,null,"Crop growth stage (BBCH codes) [% crop interception] ****"]
[null,"Crop","References","Drift percentage *","Copper","Manganese","Zinc","Low","High","Medium","Bare soil, BBCH 00-09","Minimal crop cover, BBCH 10-19","Intermediate crop cover, BBCH 20-39","Full canopy, BBCH 40-89"]
[null,null,null,"[%]","[g/t]","[g/t]","[g/t]","[t/ha/y]","[t/ha/y]","[t/ha/y]"]
[null,"SPERC 1: Outdoor use - direct application of solid fertilizers to soil; surface spreading",null,0,null,null,null,null,null,null,0,10,25,40]
[null,"SPERC 2: Outdoor use - direct application of solid or liquid fertilizers to soil; incorporation, placement, mixing, seed treatment, drip irrigation",null,0,null,null,null,null,null,null,0,0,0,0]
[null,"SPERC 3: Outdoor use - application of fertilizers by helicopter",null,33.200000000000003,null,null,null,null,null,null,0,20,50,70]
[null,"SPERC 4: Outdoor use - spray application of liquid fertilizers; soil surface spreading, sprinkler, pivot, foliar spray, slurry",null,15.725,null,null,null,null,null,null,0,20,40,65]
[null,"Generic crop"]
[null,"---------"]
[null,"Cereals, spring","13, 18",2.7589999999999999,11,31,24.666666666666668,1.86,6.4640000000000004,3.5239000000000003,0,0,20,70]
[null,"Cereals, winter","13, 18, 20",2.7589999999999999,11,21.143333333333334,24,1.2767500000000001,8.0313333333333343,4.1634166666666665,0,0,20,70]
[null,"Citrus","8, 10, 16, 18",15.725,0.53,0.5625,0.85,8.8338640090749667,43.247496121938511,20.264226552337071,0,80,80,80]
[null,"Field beans","16",2.7589999999999999,13,13,38,0.57366666666666699,5.42,2.4566666666666661,0,25,40,70]
[null,"Grass / alfalfa","13, 16",2.7589999999999999,6.5,63,39,1.9728333333333334,27.35,5.2894166666666669,0,40,60,75]
[null,"Hops","14",19.326000000000001,319,84,38,0.65800000000000003,1.9633333333333336,1.3908333333333334,0,20,50,70]
[null,"Legumes","16",2.7589999999999999,11,13,46,1.2873999999999999,4.4317333333333337,2.3303333333333334,0,25,50,70]
[null,"Maize (grain)","13, 16, 11, 18",2.7589999999999999,5.3,9.3000000000000007,17.5,3.8126666666666673,11.214666666666666,7.4935,0,25,50,75]
[null,"Maize (silage)","11, 17",2.7589999999999999,7.65,91.8,35.200000000000003,7.495333333333333,52.746666666666655,33.869999999999997,0,25,50,75]
[null,"Oil seed rape, spring","18",2.7589999999999999,5,33,30,1.7133333333333329,2.9666666666666668,1.9313333333333333,0,40,70,75]
[null,"Oil seed rape, winter","18",2.7589999999999999,5,33,30,2.044,4.043333333333333,2.98,0,40,70,75]
[null,"Olives","5",15.725,null,2.0499999999999998,3.1,1.22371601932422,8.6965156900946603,1.9066725545630185,0,70,70,70]
[null,"Pome / stone fruit, (early)","2, 4, 9, 12, 13, 18, 21",29.196999999999999,0.70857142857142852,1.1400000000000001,1.6657142857142857,2.5556546263520108,20.769126768721037,8.7795087092088337,0,20,40,65]
[null,"Pome / stone fruit (late)","2, 4, 9, 12, 13, 18, 21",15.725,0.70857142857142852,1.1400000000000001,1.6657142857142857,2.5556546263520108,20.769126768721037,8.7795087092088337,0,20,40,65]
[null,"Potatoes","16, 18, 19",2.7589999999999999,3.67,15.58,1.9,10.262666666666666,44,25.607833333333339,0,15,50,70]
[null,"Soybeans","16, 6, 18",2.7589999999999999,39.75,33,36.93,0.94666666666666666,3.4893333333333336,2.2133333333333329,0,20,50,75]
[null,"Sugar beet","15, 3, 21",2.7589999999999999,0.75,8,3.5,35.880999999999993,90.350333333333325,60.747166666666672,0,20,70,75]
[null,"Sunflower","16",2.7589999999999999,9,16,46,0.74299999999999999,2.5993333333333335,2.2599999999999998,0,20,50,75]
[null,"Tobacco","13",2.7589999999999999,21,184,69,1.3836666666666666,2.5836666666666663,1.9629999999999999,0,20,70,75]
[null,"Vegetables, bulb","1, 13",2.7589999999999999,1,2.1749999999999998,3.9950000000000001,7.687947700447701,29.544438366023396,17.295045801257501,0,10,25,40]
[null,"Vegetables, fruiting","13, 18, 21",2.7589999999999999,1.4033333333333333,2.4874999999999998,3.2150000000000003,12.71914015864888,234.0520740791037,38.59363411943508,0,25,50,70]
[null,"Vegetables, leafy","11, 13, 21",2.7589999999999999,1.2625,3.5925000000000002,4.5999999999999996,8.2211226090098943,38.813825583027956,18.394806691444575,0,25,40,70]
[null,"Vegetables, root",21,2.7589999999999999,0.45,1.43,2.4,10.577772347061273,51.017396312723719,27.303997672025854,0,25,50,70]
[null,"Vines, early applications",21,2.6989999999999998,1.27,0.71,0.7,1.7441336441336441,14.350577248446468,6.0514547473300047,0,40,50,60]
[null,"Vines, late applications",21,8.0280000000000005,1.27,0.71,0.7,1.7441336441336441,14.350577248446468,6.0514547473300047,0,40,50,60]
[null,"Forest (aerial application)","*****",33.200000000000003,0,0,0,0,0,0,0,20,50,70]
[null,null,null,null,null,null,null,null,null,null,null,null,null,""]
[null,"* Rautmann drift values, single application (Rautmann et al, 2001)"]
[null,"** Full list of all crop micronutrient concentration litarature refer to sheet \"References_cropconc\""]
[null,"*** Eurostat database on Crop statistics (average yield data 2012-'14)"]
[null,"**** EFSA DegT50 guidance document (2014)"]
[null,"***** No crop offtake, considering long life span of forest trees"]
[]
[null,null,null,null,null,null,null,null,null,null,"Tool developed by ARCHE Consulting © 2017"]

{"sheet":"SpERC details","index":7,"n_rows":19,"n_cols":9,"rows_kept":19,"cut":false,"hidden":false,"merged":[]}
[null,"FERTILIZER ENVIRONMENTAL EXPOSURE (FEE) TOOL"]
[null,"SPERC DETAILS"]
[]
[null,"Runoff scenario","% runoff 30 days","% runoff, incl. soil incorporation",null,"Vapour pressure","Volatilization (%)"]
[null,"SPERC 1: Outdoor use - direct application of solid fertilizers to soil; surface spreading",{"$f":"IF(100-100*EXP(-Ksoil_water_runoff*30)<5,100-100*EXP(-Ksoil_water_runoff*30),5)","v":3.8542077816643427E-2},{"$f":"IF(100-100*EXP(-Ksoil_water_runoff_soil_incorp*30)<5,100-100*EXP(-Ksoil_water_runoff_soil_incorp*30),5)","v":8.0812338533320371E-3},null,"Default (inorganics)",0,null,"Single"]
[null,"SPERC 2: Outdoor use - direct application of solid or liquid fertilizers to soil; incorporation, placement, mixing, seed treatment, drip irrigation",0,0,null,"< 0.01 mPa",1,null,"Multiple"]
[null,"SPERC 3: Outdoor use - application of fertilizers by helicopter",{"$f":"IF(100-100*EXP(-Ksoil_water_runoff*30)<5,100-100*EXP(-Ksoil_water_runoff*30),5)","v":3.8542077816643427E-2},{"$f":"IF(100-100*EXP(-Ksoil_water_runoff_soil_incorp*30)<5,100-100*EXP(-Ksoil_water_runoff_soil_incorp*30),5)","v":8.0812338533320371E-3},null,"0.01 - 0.1 mPa",10]
[null,"SPERC 4: Outdoor use - spray application of liquid fertilizers; soil surface spreading, sprinkler, pivot, foliar spray, slurry",{"$f":"IF(100-100*EXP(-Ksoil_water_runoff*30)<5,100-100*EXP(-Ksoil_water_runoff*30),5)","v":3.8542077816643427E-2},{"$f":"IF(100-100*EXP(-Ksoil_water_runoff_soil_incorp*30)<5,100-100*EXP(-Ksoil_water_runoff_soil_incorp*30),5)","v":8.0812338533320371E-3},null,"0.1 - 1 mPa",20,null,50]
[null,null,null,null,null,"1 - 10 mPa",50,null,75]
[null,null,null,null,null,"> 10 mPa",100,null,90]
[]
[null,null,null,null,null,null,null,null,60]
[null,null,null,null,null,null,null,null,80]
[]
[null,null,null,null,null,null,null,null,"yes"]
[null,null,null,null,null,null,null,null,"no"]
[]
[]
[null,null,null,null,null,null,"Tool developed by ARCHE Consulting © 2017"]

{"sheet":"Micro-nutrient endpoints","index":8,"n_rows":47,"n_cols":16,"rows_kept":47,"cut":false,"hidden":true,"merged":[]}
[null,"FERTILIZER ENVIRONMENTAL EXPOSURE (FEE) TOOL"]
[null,"MICRO-NUTRIENT STANDARD PARAMETERS"]
[]
[null,"Micro-nutrient *",null,"Substance properties",null,null,null,null,null,"Exposure assessment (PEC regional)",null,null,null,"Effect assessment"]
[null,null,null,"Molecular weight \n[g/mol]","Solubility at 25°C [mg/L] **","Vapour pressure at 25°C [Pa] **","Henry coefficient [Pa*m3/mol] *","Kpsoil [L/kg dw]","Kp susp matter [L/kg dw]","PEC soil [mg/kg dw] ***","PEC freshwater [µg/L]","PEC sediment [mg/kg dw]","Added/total approach","PNEC soil [mg/kg dw]","PNEC freshwater [µg/L]","PNEC sediment [mg/kg dw] ****"]
[null,"Copper","Cu",63.55,100,9.9999999999999995E-7,3.9999999999999998E-6,2120,30246,14,2.9,67.5,"TOTAL",65,7.8,87]
[null,"Manganese","Mn",54.94,100,9.9999999999999995E-7,3.9999999999999998E-6,1355,{"$f":"POWER(10,4.45)","v":28183.829312644593},0,0,0,"ADDED",25.1,12.8,36.1]
[null,"Zinc","Zn",65.38,100,9.9999999999999995E-7,3.9999999999999998E-6,158.5,110000,41.3,3.4,45,"ADDED",107,20.6,235.6]
[null,"-> Other",null,"Provide manual input","Provide manual input","Provide manual input","Provide manual input (or enter mol.weight, solubility and vapour pressure)","Provide manual input for Kpsoil or Koc","Provide manual input","Provide manual input","Provide manual input","Provide manual input",null,"Provide manual input","Provide manual input","Provide manual input"]
[null,"* Unless otherwise stated, micro-nutrient properties are based on information from the REACH dissemination website for relevant substances (see table below); please check carefully for consistency with most recent dossier information"]
[null,"** Default values for inorganics from R7-13-2 Information requirements, metals"]
[null,"*** PEC soil regional selected from GEMAS dataset"]
[null,"**** The PNEC sediment for MnSO4 has been calculated according to the equilibrium approach based on the PNEC water from MnSO4 (expressed as µg Mn/L), a Kd value for Mn adsorption to suspended matter (from Vesely et al., 2001) and an additional assessment factor 10."]
[]
[]
[]
[]
[null,"Name","Formula","CAS nr","EC nr"]
[null,"Copper"]
[null,"Copper chloride","CuCl","7758-89-6","231-842-9"]
[null,"Copper di(acetate)","Cu(CH3COO)2","142-71-2, \n6046-93-1","205-553-3"]
[null,"Copper dichloride","CuCl2","7447-39-4, \n10125-13-0","231-210-2"]
[null,"Copper dihydroxide","Cu(OH)2","20427-59-2","243-815-9"]
[null,"Copper dinitrate","Cu(NO3)2","3251-23-8, \n10031-43-3","221-838-5"]
[null,"Copper oxide","CuO","1317-38-0","215-269-1"]
[null,"Copper sulphate","CuSO4","7758-98-7, \n7758-99-8","231-847-6"]
[null,"Copper(2+) ion hydroxide nitrate","Cu(OH)(NO3)","12158-75-7","439-590-3"]
[null,"Copper(II) carbonate--copper(II) hydroxide (1:1)","CuCO3-Cu(OH)2","12069-69-1","235-113-6"]
[null,"Dicopper oxide","Cu2O","1317-39-1","215-270-7"]
[null,"Dicopper chloride trihydroxide","Cu2Cl(OH)3","1332-40-7, \n1332-65-6","215-572-9"]
[null,"Dicopper hydroxide phosphate","Cu2(OH)(PO4)","12158-74-6","235-285-2"]
[null,"Zinc"]
[null,"Zinc bis(dihydrogen phosphate)","Zn(H2PO4)2","13598-37-3","237-067-2"]
[null,"Trizinc bis(orthophosphate)","Zn3(PO4)2","7779-90-0","231-944-3"]
[null,"Zinc borate","ZnHBO3","1332-07-6","215-566-6"]
[null,"Zinc chloride","ZnCl2","7646-85-7","231-592-0"]
[null,"Zinc hydroxide","Zn(OH)2","20427-58-1","243-814-3"]
[null,"Zinc nitrate","Zn(NO3)2","7779-88-6, \n10196-18-6","231-943-8"]
[null,"Zinc oxide","ZnO","1314-13-2, \n7440-66-6","215-222-5"]
[null,"Zinc sulphate","ZnSO4","7446-19-7, \n7446-20-0, \n7733-02-0","231-793-3"]
[null,"Ammonium zinc chloride","Zn(NH4)2Cl4","52628-25-8","258-054-8"]
[null,"Carbonic acid, zinc salt, basic","Zn(x/2+y).(OH)x.(CO3)y","51839-25-9","257-467-0"]
[null,"Zinc carbonate","ZnCO3","3486-35-9","222-477-6"]
[null,"Manganese"]
[null,"Manganese sulphate","MnSO4","7785-87-7, \n10034-96-5","232-089-9"]
[]
[null,null,null,null,null,null,null,null,null,null,null,null,"Tool developed by ARCHE Consulting © 2017"]

{"sheet":"Biodegradation","index":9,"n_rows":18,"n_cols":7,"rows_kept":18,"cut":false,"hidden":false,"merged":[[5,1,9,1]]}
[null,null,"FERTILIZER ENVIRONMENTAL EXPOSURE (FEE) TOOL"]
[null,null,"BIODEGRADATION IN SOIL AND SURFACE WATER"]
[]
[null,null,"Half-lives (days) based on results from standardised biodegradation screening tests *"]
[]
[null,"SOIL","Kpsoil (L/kg)","Not biodegradable","Readily biodegradable","Readily biodegradable, failing 10-d window ","Inherently biodegradable"]
[null,null,"Kp ≤ 100",1000000,30,90,300]
[null,null,"Kp 100 - 1000",1000000,300,900,3000]
[null,null,"Kp 1000 - 10000",1000000,3000,9000,30000]
[null,null,"Kp 10000 - 100000",1000000,30000,90000,300000]
[null,null,"SURFACE WATER",1000000,15,50,150]
[]
[null,null,"* Table adapted from REACH guidance R.16, Table R.16-12 (soil) and Table R.16-11 (surface water)"]
[]
[]
[]
[]
[null,null,null,null,null,null,"Tool developed by ARCHE Consulting © 2017"]

{"sheet":"References_cropconc","index":10,"n_rows":22,"n_cols":6,"rows_kept":22,"cut":false,"hidden":false,"merged":[]}
["Reference #","Author(s)","Year","Title","Journal/Book/Website","Publisher"]
[1,"Andrioli, F.F. et al.",2008,"Curve of growth and uptake for the garlic crop under field conditions","Scientia Agraria 9(3): 385-393;\nhttp://revistas.ufpr.br/agraria/article/view/11538"]
[2,"Aydinalp, C. & Marinova, S.",2012,"Concentration of Cu and Zn in some fruits and vegetables grown in Northwestern Turkey","Bulgarian Journal of Agricultural Science 18(5): 749-751;\nhttp://www.agrojournal.org/18/05-15-12.pdf"]
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